Alkaline Earth Metal Bisamides Based on Unsymmetrical Acenaphthene-1,2-diimine

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Abstract

Reduction of diimine ArMid-bian (L) (ArMid-bian = (1-[2,6-dibenzhydryl-4-methylphenyl]-2-[2,6-di-iso-propylphenyl]iminoacenaphthene) with excess magnesium, calcium, strontium or barium in the presence of catalytic amounts of the corresponding iodides leads to the formation of complexes [(ArMid-bian)Mg(Thf)(Dme)] (I), [(ArMid-bian)Ca(Dme)2] (II), [(ArMid-bian)Sr(Dme)2] (III) and [(ArMid-bian)Ba(Dme)2] (IV) containing the dianion ArMid-bian. Compounds L, I–IV were characterized by IR and NMR spectroscopy, as well as elemental analysis and single crystal X-ray analysis (CIF files CCDC 2440721 (L), 2440722 (I), 2440723 (II), 2440724 (III), 2440725 (IV)).

About the authors

A. A Bazanov

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: b.andrey2010@yandex.ru
ORCID iD: 0009-0002-9576-083X
PhD in Chemistry, Researcher Nizhny Novgorod, Russian Federation

A. A Skatova

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: skatova@iomc.ras.ru
ORCID iD: 0009-0004-8749-4791
Dr. Sci. (Chemistry), Leading Researcher Nizhny Novgorod, Russian Federation

E. V Baranov

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: bar@iomc.ras.ru
ORCID iD: 0000-0002-1923-6879
PhD in Chemistry, Researcher Nizhny Novgorod, Russian Federation

I. L Fedushkin

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: igorfed@iomc.ras.ru
ORCID iD: 0000-0003-2664-2266
Dr. Sci. (Chemistry), Full Member of the Russian Academy of Sciences, Director, Chief Researcher Nizhny Novgorod, Russian Federation

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