Cadmium(II) Metal-Organic Frameworks Based on Iodine-Substituted Terephthalic Acid Derivatives and 1,1'-(1,4-Butanediyl)-bis-imidazole

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Abstract

Two metal-organic frameworks based on Cd(II) and 2-iodo-(2-I-Bdc) and 2,5-diodo-(2,5-I-Bdc)terephthalate were obtained: {[Cd(2-I-Bdc)(Bbi)]} (I) and {[Cd2(2,5-I-Bdc)2(DMF)2(Bbi)]} (II) (Bbi = 1,1'-(1,4-butanediyl)bis(imidazole)). The structures of both complexes were established by X-ray diffraction (CCDC no. 2258217 (I) and 2257566 (II)).

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About the authors

M. A. Bondarenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; South Ural State University

Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk; Chelyabinsk

A. S. Zaguzin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; South Ural State University

Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk; Chelyabinsk

P. A. Abramov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk

I. V. Korol’kov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk

D. A. Zherebtsov

South Ural State University

Email: adonin@niic.nsc.ru
Russian Federation, Chelyabinsk

V. P. Fedin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk

S. A. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; South Ural State University; Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk; Chelyabinsk; Irkutsk

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Supplementary files

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2. Fig. 1. Experimental (above) and calculated from the X-ray diffraction data (below) powder diffractograms for I.

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3. Fig. 2. The structure of the binuclear building blocks in structure I.

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4. Fig. 3. Three-dimensional structure I.

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5. Fig. 4. The structure of the binuclear building block {Cd2(2,5-I-Bdc)Bbi(DMF)2} in the crystal structure of complex II.

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6. Fig. 5. Crystal packing of complex II.

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