Мақаланы E-mail арқылы жіберу SYNTHESIS AND STRUCTURE OF NEW [5]FERROCENOPHANE
- Авторлар: Medved’ko A.V.1, Churakov A.V.2, Krut’ko D.P.3, Vatsadze S.Z.1
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Мекемелер:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Department of Chemistry, Lomonosov Moscow State University
- Шығарылым: Том 513, № 1 (2023)
- Беттер: 62-66
- Бөлім: CHEMISTRY
- URL: https://transsyst.ru/2686-9535/article/view/651932
- DOI: https://doi.org/10.31857/S2686953523600095
- EDN: https://elibrary.ru/CCEEDQ
- ID: 651932
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Аннотация
The first example of intramolecular diastereoselective domino reaction of ferrocene 1,1'-bis-enone to [5]ferrocenophane initiated with sodium ethylate was found. The product is [5]ferrocenophane with two pyridyl and one ethoxy substituents arranged asymmetrically in five carbon bridge. Diffraction studies showed that ferrocene is in almost ideal eclipsed conformation. The fan conformation found in the crystal is also preserved in solution, which was determined by NMR spectroscopy.
Негізгі сөздер
Авторлар туралы
A. Medved’ko
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: zurabych@gmail.com
Russian Federation, 119991
A. Churakov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zurabych@gmail.com
Russian Federation, 119991
D. Krut’ko
Department of Chemistry, Lomonosov Moscow State University
Email: zurabych@gmail.com
Russian Federation, 119991
S. Vatsadze
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: zurabych@gmail.com
Russian Federation, 119991
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