Selective Extraction of Lithium Cations From Mixture of Alkali Metal Chlorides Using Electrobaromembrane Process

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅或者付费存取

详细

The problem of low-reagent separation of Na+, K+ and Li+ cations is becoming increasingly important in connection with the search for new technologies for the extraction of lithium from brines and the recovery of this valuable element from already used energy sources. This paper presents the results of testing the electrobaromembrane process, in which the gradients of the electric field and pressure field are directed in opposite directions. The experiments were carried out in a laboratory flow cell, the desalting and concentration chambers of which are separated by a track-etched membrane and limited by MA-41 anion-exchange membranes. The working area of each membrane is 30 cm2. The processed solution contains 70, 75 and 55 mmol/L LiCl, KCl and NaCl, respectively. It has been shown that at a current density of 11,7 mA/cm2 and a pressure difference of 0.20 bar in the desalting circuit, it is possible to ensure an accumulation rate of Li+ cations equal to 0,05 mol/(m2 h), and a rate of loss of Na+ and K+ cations from this circuit , equal to minus 0,09 and minus 0,25 mol/(m2h), respectively. Factors that can influence the efficiency of separation of Li+ and Na+, K+ are considered.

全文:

受限制的访问

作者简介

D. Butylskii

Kuban State University

Email: v_nikonenko@mail.ru
俄罗斯联邦, 149 Stavropolskaya St., 350040 Krasnodar

V. Troitskiy

Kuban State University; Platov South-Russian State Polytechnic University (NPI)

Email: v_nikonenko@mail.ru
俄罗斯联邦, 149 Stavropolskaya St., 350040 Krasnodar; 132 Prosveschenia str., 346428 Novocherkassk

N. Smirnova

Platov South-Russian State Polytechnic University (NPI)

Email: v_nikonenko@mail.ru
俄罗斯联邦, 132 Prosveschenia str., 346428 Novocherkassk

N. Pismenskaya

Kuban State University

Email: v_nikonenko@mail.ru
俄罗斯联邦, 149 Stavropolskaya St., 350040 Krasnodar

P. Apel

Joint Institute for Nuclear Research

Email: v_nikonenko@mail.ru
俄罗斯联邦, 6 Joliot-Curie St., 141980 Dubna

I. Blonskaya

Joint Institute for Nuclear Research

Email: v_nikonenko@mail.ru
俄罗斯联邦, 6 Joliot-Curie St., 141980 Dubna

V. Nikonenko

Kuban State University

编辑信件的主要联系方式.
Email: v_nikonenko@mail.ru
俄罗斯联邦, 149 Stavropolskaya St., 350040 Krasnodar

参考

  1. Bradley D.C., Stillings L.L., Jaskula B.W., Munk L., McCauley A.D. Lithium, 1802K, Reston, VA, 2017.
  2. Zhang Y., Yu D., Jia C., Sun L., Tong A., Wang Y., Wang Y., Huang L., Tang J. // Desalination. 2023. V. 66. P. 116891.
  3. Рябцев А. Д., Коцупало Н. П., Вахромеев А. Г., Комин М. Ф. // Рациональное освоение недр. 2013. №. 1. С. 44–51.
  4. Gabra G.G., Torma A.E. // Hydrometallurgy. 1978. V. 3. №. 1. P. 23–33.
  5. Shi D., Zhang L., Peng X., Li L., Song F., Nie F., Ji L., Zhang Y. // Desalination. 2018. V. 441. P. 44–51.
  6. Besserguenev A.V., Fogg A.M., Francis R.J., Price S.J., Hare D. O’, Isupov V.P., Tolochko B.P. // Chem. Mater. 1997. V. 9. №. 1. P. 241–247.
  7. Chitrakar R., Kanoh H., Miyai Y., Ooi K. // ChemInform. 2001. V. 32. №. 4. P. 3151–3157.
  8. Guo Y., Yu J., Su H., Lin S. // Desalination. 2001. V. 571. №. 117113.
  9. Wang J., Yue X., Wang P., Yu T., Du X., Hao X., Abudula A., Guan G. // Renew. Sust. Energ. Rev. 2022. V. 154. №. 111813.
  10. Zhang Y., Xu R., Wang L., Sun W., Guan G. // Miner. Eng. 2022. V. 180. №. 107468.
  11. Lai X., Xiong P., Zhong H. // Miner. Eng. 2020. V. 192. №. 105252.
  12. Zhu R., Wang S., Srinivasakannan C., Li S., Yin S., Zhang L., Jiang X., Zhou G., Zhang N. // Environ. Chem. Lett. 2023. V. 21. №. 3. P. 1611–1626.
  13. Lide D.R., CRC Handbook of Chemistry and Physics 86TH Edition. 2005.
  14. Wei X., Gao W., Wang Y., Wu K., Xu T. // Sep. Purif. Technol. 2022. V. 280. №. 119909.
  15. Бутыльский Д. Ю., Письменская Н. Д., Никоненко В. В. // Успехи химии. 2023. Т. 92. С. 4. (англоязычная версия: Butylskii D.Y., Dammak L., Larchet C., Pismenskaya N.D., Nikonenko V.V. // Russ. Chem. Rev. 2023. V. 92. P. 5074.)
  16. Gao S.-L., Qin Z.-X., Wang B.-F., Huang J., Xu Z.-L., Tang Y.-J. // Desalination. 2024. V. 572. №. 117142.
  17. Ying J., Lin Y., Zhang Y., Yu J. // ACS ES and T Water. 2023. V. 3. №. 7. P. 1720–1739.
  18. Wang H., Zeng G., Yang Z., Chen X., Wang L., Xiang Y., Zeng X., Feng Z., Tang B., Yu X., Zeng Y. // Sep. Purif. Technol. 2024. V. 330. №. 125254.
  19. Figueira M., Rodríguez-Jiménez D., López J., Reig M., Cortina J. L., Valderrama C. // Desalination. 2023. V. 549. №. 1116321.
  20. Bazrgar Bajestani M., Moheb A., Dinari M. // Desalination. 2020. V. 486. №. 114476.
  21. Sharma P.P., Yadav V., Rajput A., Gupta H., Saravaia H., Kulshrestha V. // Desalination. 2020. V. 496. №. 114755.
  22. Ying J., Luo M., Jin Y., Yu J. // Desalination. 2020. V. 492. №. 1146215.
  23. Brewer A.K., Madorsky S.L., Westhaver J.W. // Science. 1946. V. 104. №. 2694. P. 156 –157.
  24. Forssell P., Kontturi K. // Sep. Purif. Technol. 1983. V. 18. №. 3. P. 205 – 214.
  25. Kontturi K., Pajari H. // Sep. Purif. Technol. 1986. V. 21. №. 10. P. 1089–1099.
  26. Tang C., Bondarenko M.P., Yaroshchuk A., Bruening M.L. // J. Memb. Sci. 2021. V. 638. № 119684.
  27. Butylskii D.Y., Pismenskaya N.D., Apel P.Y., Sabbatovskiy K.G., Nikonenko V.V. // J. Memb. Sci. 2021. V. 635. №. 119449.
  28. Butylskii D., Troitskiy V., Chuprynina D., Dammak L., Larchet C., Nikonenko V. // Membranes. 2021. V. 13. №. 5. Art. 509.
  29. Сарапулова В.В., Пасечная Е.Л., Титорова В.Д., Письменская Н.Д., Апель П.Ю., Никоненко В.В. // Мембраны и мембранные технологии. 2020. Т. 10. № 5. С. 350–370. (англоязычная версия: Sarapulova V. V., Pasechnaya E.L., Titorova V.D., Pismenskaya N.D., Apel P.Y., Nikonenko V. V. // Membr. Membr. Technol. 2020. V. 2. P. 332–350.)
  30. Kozhina E., Panov D., Kovalets N., Apel P., Bedin S. // Nanotechnology. 2023. V. 35. № 3. Art. 035601.
  31. Flerov G.N., Apel P.Y., Didyk A.Y., Kuznetsov V.I., Oganesyan R.T. // Soviet At. Energy. 1989. V. 67, P. 763–70.
  32. Apel P. Y. //Encyclopedia of membrane science and technology. 2013. P. 1–25.
  33. Monopolar membranes. http://www.azotom.ru/monopolyarnye-membrany/ (accessed September 26, 2023).
  34. Сарапулова В.В., Титорова В.Д., Никоненко В.В., Письменская Н.Д. // Мембраны и мембранные технологии. 2019. Т. 9. № 3. С. 198–213. (англоязычная версия: Sarapulova V.V., Titorova V.D., Nikonenko V.V., Pismenskaya N.D. // Membr. Membr. Technol. 2019. V. 1. № 3. P. 168–182.)
  35. Белей И., Кармацких С. А., Речапов Д. А., Цыпкин Е. Б., Коростелев А. С., Антоненко Д. В. // Строительство нефтяных и газовых скважин на суше и на море. 2018. №. 4. С. 23–30.
  36. Кислый, А. Г., Бутыльский, Д. Ю., Мареев, С. А., & Никоненко, В. В. // Мембраны и мембранные технологии. 2021. Т. 11. № 2. С. 146–154. (англоязычная версия: Kislyi A.G., Butylskii D.Y., Mareev S.A., Nikonenko V.V. // Membr. Membr. Technol. 2021. V. 3. № 2. P. 131–138.)
  37. Zhao Y., Xiang X., Wang M., Wang H., Li Y., Li J., Yang H. // Desalination. 2021. V. 512. №. 115126.
  38. Tang C., Yaroshchuk A., Bruening M. L. // Chem. Commun. 2020. V. 56. №. 74. P. 10954 –10957.

补充文件

附件文件
动作
1. JATS XML
下载
2. Fig. 1. Schematic diagram of the experimental setup (a): laboratory cell (1), current source (2), pumps (3), intermediate tanks of circuits I and II (4), pressure gauges (5), valve for creating excess pressure (6), intermediate tank of the electrode chamber circuits (7). Figure (b) shows a frame with a separator separating the membranes.

下载 (451KB)
索引源数据
3. Fig. 2. Electrical conductivity of solutions in intermediate capacities of circuits of chambers I and II depending on the duration of the electro-baromembrane process carried out at a current density of 11.7 mA/cm2 (a) and 13.3 mA/cm2 (b). The pressure difference between chambers I and II in both experiments was 0.2 bar.

下载 (261KB)
索引源数据
4. Fig. 3. Change in the number of moles of LiCl (a), KCl (b) and NaCl (c) in circuit I depending on the duration of the electrobaromembrane process carried out at a current density of 11.7 mA/cm2 (curves 1) and 13.3 mA/cm2 (curves 2). The lines in the figures serve as a guide for the eyes.

下载 (266KB)
索引源数据
5. Fig. 4. Schematic representation of the distribution of concentrations and values of the velocities of movement of competing ions Li+, Na+ and K+ at the beginning (a) of the process and after 40 hours (b).

下载 (143KB)
索引源数据

版权所有 © Russian Academy of Sciences, 2024