Ion Transport Asymmetry in Hybrid Membranes MF-4SK with Gradient Distribution of Hydrated Silicon Oxide, Including Modified Surface

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The paper presents the results of investigation of properties of hybrid materials based on homogeneous membrane MF-4SC with gradient distribution of dopant along the thickness. Hydrated silicon oxide nanoparticles, including those with a functionalized surface containing proton acceptor groups, were used as dopant. The presence of asymmetry of diffusion permeability of HCl and NaCl solutions of the studied membranes was revealed. It is shown that the diffusion permeability depends on the orientation of the membrane with respect to the electrolyte solution and the asymmetry reaches 65%. Depending on the surface properties of the introduced silicon oxide (on the nature and size of grafted groups) the direction of preferential ion transport changes. The causes of the diffusion permeability asymmetry and factors determining its direction are described.

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Sobre autores

E. Safronova

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: safronova@igic.ras.ru
Rússia, Leninsky Prospekt, 31, Moscow, 119991

Yu. Karavanova

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: safronova@igic.ras.ru
Rússia, Leninsky Prospekt, 31, Moscow, 119991

I. Stenina

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: safronova@igic.ras.ru
Rússia, Leninsky Prospekt, 31, Moscow, 119991

D. Voropaeva

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: safronova@igic.ras.ru
Rússia, Leninsky Prospekt, 31, Moscow, 119991

D. Safronov

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: safronova@igic.ras.ru
Rússia, Leninsky Prospekt, 31, Moscow, 119991

A. Lysova

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: safronova@igic.ras.ru
Rússia, Leninsky Prospekt, 31, Moscow, 119991

V. Krutko

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: safronova@igic.ras.ru
Rússia, Leninsky Prospekt, 31, Moscow, 119991

A. Manin

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: safronova@igic.ras.ru
Rússia, Leninsky Prospekt, 31, Moscow, 119991

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2. Fig. 1. Scheme for measuring the diffusion permeability of hybrid membranes with a gradient distribution of the dopant depending on the orientation relative to the diffusing solution.

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3. Fig. 2. TEM micrograph of the hybrid membrane MF-4SK. The composition of the modified layer: MF-4SK + 3 wt.% SiO₂(5 mol.% 3-(2-imidazolin-1-yl)propyl-, R2). The concentration of modifying groups is calculated from the concentration of SiO₂ in the modified layer.

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4. Fig. 3. Dependence of proton conductivity on temperature for MF-4SK membranes with different SiO₂ content in the modified layer (a) and membranes containing 3 wt.% SiO₂ in the modified layer with a modified surface with 3-aminopropyl- (R1) and 3-(2-imidazolin-1-yl)propyl- (R2) groups (b). The composition of the modified layer is shown in the figures. The changes were carried out in contact with water.

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5. Fig. 4. Diffusion permeability of the studied membranes (columns) in 0.1 M HCl (a) and NaCl (b) solutions and the diffusion permeability asymmetry coefficient (dots) for membranes with non-uniform dopant distribution across the entire membrane thickness. The content of hydrated silicon oxide in the modified layer (wt.%) is shown in the figure.

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6. Fig. 5. Schematic representation of the system of pores and channels in the membrane from the unmodified (left part of the figure) and modified (right part of the figure) sides.

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