Reaction of 1-antipyryl-4-aroyl-5-methoxyrabonyl-1 Н -pyrrol-2,3-diones with  N -substituted- and  N -unsubstituted 3-amino-5,5-dimethylcyclohexen-2-ones

V. A. Lyadov; Лядов Вадим Александрович; E. S. Denislamova; Денисламова Екатерина Сергеевна; A. N. Maslivets; Масливец Андрей Николаевич

doi:10.31857/S0514749225020077

Reaction of 1-antipyryl-4-aroyl-5-methoxyrabonyl-1Н-pyrrol-2,3-diones with N-substituted- and N-unsubstituted 3-amino-5,5-dimethylcyclohexen-2-ones

Authors: Lyadov V.A.¹, Denislamova E.S.¹, Maslivets A.N.²
Affiliations:
1. Perm National Research Polytechnic University
2. Perm State University
Issue: Vol 61, No 2 (2025)
Pages: 172-177
Section: Articles
URL: https://transsyst.ru/0514-7492/article/view/684323
DOI: https://doi.org/10.31857/S0514749225020077
EDN: https://elibrary.ru/DGTKBY
ID: 684323

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Abstract

The article considers nucleophilic transformations of N-antipyryl-substituted-1H-pyrrole-2,3-diones under the action of dimedone imine and N-substituted dimedone imines, acting as 1,3-CH,NH-binucleophilic reagents, with the formation of 1'-antipyryl-3'-aroyl-4'-hydroxy-6,6-dimethyl-6,7-dihydrospiro[indole-3,2'-pyrrole]-2,4,5'(1H,1'H,5H)-triones and 1'-antipyryl-1-aryl-3'-aroyl-4'-hydroxy-6,6-dimethyl-6,7-dihydrospiro[indole-3,2'-pyrrole]-2,4,5'(1H,1'H,5H)-triones.

Keywords

monocyclic 1H-pyrrole-2, 3-diones, nucleophilic transformations, dimedone, imines, enamine, spiroheterocyclization

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About the authors

V. A. Lyadov

Perm National Research Polytechnic University

Author for correspondence.
Email: vadim.lyadov2017@yandex.ru
ORCID iD: 0000-0002-7267-7577
Russian Federation, prosp. Komsomolskii, 29, Perm, 614990

E. S. Denislamova

Perm National Research Polytechnic University

Email: vadim.lyadov2017@yandex.ru
ORCID iD: 0000-0003-1220-3625
Russian Federation, prosp. Komsomolskii, 29, Perm, 614990

A. N. Maslivets

Perm State University

Email: vadim.lyadov2017@yandex.ru
ORCID iD: 0000-0001-7148-4450
Russian Federation, ul. Bukireva, 15, Perm, 614068

References

Lyadov V.A., Shavrina N.V., Denislamova E.S., Maslivets A.N. ChemChemTech. 2024, 67, 19–26. doi: 10.6060/ivkkt.20246703.6846
Lyadov V.A., Makrushin D.E., Denislamova E.S., Maslivets A.N., Triandafilova G.A., Solodnikov S.I. ChemChemTech. 2024, 67, 17–23. doi: 10.6060/ivkkt.20246705.6939
Лядов В.А., Шаврина Н.В., Денисламова Е.С., Масливец А.Н. ЖОрХ. 2024, 60, 523-526. [Lyadov V.A., Shavrina, N.V., Denislamova E.S. et al. Russ. J. Org. Chem. 2024, 60, 747–749.] doi: 10.1134/S1070428024040262
Червяков А.В. Дис. … канд. хим. наук. Пермь. 2017
Банникова Ю.Н., Масливец А.Н. ЖОрХ. 2006, 42, 787–788. [Bannikova Yu.N. and Maslivets A.N., Russ. J. Org. Chem. 2005, 42, 787–788.] doi: 10.1134/S107042800605023X
Денисламова Е.С., Банникова Ю.Н., Масливец А.Н. ЖОрХ. 2008, 44, 777–778. [Denislamova E.S., Bannikova Yu.N., and Maslivets A.N., Russ. J. Org. Chem. 2008, 44, 772–773.] doi: 10.1134/S1070428008050278
Денисламова Е.С., Лядов В.А., Макрушин Д.Е., Рябов В.Г., Дмитриев М.В., Масливец А.Н. ЖОрХ. 2023, 59, 535–540. [Denislamova E.S., Lyadov V.A., Makrushin D.E., Ryabov V.G., Dmitriev M.V., Maslivets A.N. Russ. J. Org. Chem. 2023, 59, 647–651.] doi: 10.31857/S0514749223040122