Synthesis, Structures, and Spectral Properties of Octa(2,6-difluorophenyl)tetraazaporphyrin and Its Cu(II) and Ni(II) Complexes

A. I. Rusanov; Русанов А. И.; N. V. Chizhova; Чижова Н. В.; A. E. Likhonina; Лихонина А. Е.; N. Zh. Mamardashvili; Мамардашвили Н. Ж.

doi:10.31857/S0044457X23600329

Synthesis, Structures, and Spectral Properties of Octa(2,6-difluorophenyl)tetraazaporphyrin and Its Cu(II) and Ni(II) Complexes

Authors: Rusanov A.I.¹, Chizhova N.V.¹, Likhonina A.E.¹, Mamardashvili N.Z.¹
Affiliations:
1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 8 (2023)
Pages: 1050-1058
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://transsyst.ru/0044-457X/article/view/665209
DOI: https://doi.org/10.31857/S0044457X23600329
EDN: https://elibrary.ru/HNDCUU
ID: 665209

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Abstract

Octa(2,6-difluorophenyl)tetraazaporphyrinate magnesium(II) has been treated with 96% sulfuric acid to obtain octa(2,6-difluorophenyl)tetraazaporphyrin. Coordination reactions of octa(2,6-difluorophenyl)tetraazaporphyrin and metal exchange of its magnesium complex with copper and nickel salts in dimethylformamide have been studied. Cu(II) and Ni(II) complexes with octa(2,6-difluorophenyl)tetraazaporphyrin have been synthesized. The resulting compounds have been identified by electron absorption, IR and 1H NMR spectroscopy, and mass spectrometry. The structures of the synthesized compounds were optimized by the DFT method. The fluorescence quantum yields of the studied compounds have been determined.

Keywords

octa(2,6-difluorophenyl)tetraazaporphyrin Mg(II) Cu(II)and Ni(II) complexes, spectral and fluorescent properties, DFT method, geometric structure

References

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