Preparation of NASICON Silico Phosphates of Composition Na1 + xZr2SixP3 – xO12 by Pyrolysis of Solution in Melt

D. N. Grishchenko; Грищенко Д. Н.; M. A. Medkov; Медков М. А.

doi:10.31857/S0044457X23600366

Preparation of NASICON Silico Phosphates of Composition Na1 + xZr2SixP3 – xO12 by Pyrolysis of Solution in Melt

作者: Grishchenko D.N.¹, Medkov M.A.¹
隶属关系:
1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences
期: 卷 68, 编号 8 (2023)
页面: 1042-1049
栏目: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://transsyst.ru/0044-457X/article/view/665208
DOI: https://doi.org/10.31857/S0044457X23600366
EDN: https://elibrary.ru/HXPQYD
ID: 665208

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详细

A new method for preparing Na1 + xZr2SixP3 – xO12 (0 < x < 3) based on pyrolysis of solution containing a mixture of organic components in rosin melt has been proposed. Effect of superstoichiometric amounts of sodium and phosphorus on the phase composition of synthesis products has been proved. It has been found that precursor for the sample of maximal purity of phase composition is prepared at molar ratio Na : Zr : Si : P = (1.15 + x) : 2 : x : (y – x), where y = 3 (1.20 + x)/(1 + x). Precursor calcination temperature is 1000°C. Different NASICON compositions without crystalline admixtures have been obtained in the range 1.5 ≤ x ≤ 2.12. The prepared samples have been studied by X-ray powder diffraction and scanning electron microscopy. The disclosed method of synthesis is promising for the preparation of NASICON as both bulk materials and thin layer coatings.

关键词

NASICON, pyrolysis of organic solutions, phase composition, solid electrolyte

作者简介

D. Grishchenko

Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences

Email: grishchenko@ich.dvo.ru
690022, Vladivostok, Russia

M. Medkov

Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: grishchenko@ich.dvo.ru
690022, Vladivostok, Russia

参考

Hong H.Y.-P. // Mater. Res. Bull. 1976. V. 11. № 2. P. 173. https://doi.org/10.1016/0025-5408(76)90073-8
Goodenough J.B., Hong H.Y.-P., Kafalas J.A. // Mater. Res. Bull. 1976. V. 11. № 2. P. 203. https://doi.org/10.1016/0025-5408(76)90077-5
Miyachi Y., Sakai G., Shimanoe K., Yamazoe N. // Sens. Actuators, B. 2003. V. 93. № 1–3. P. 250. https://doi.org/10.1016/S0925-4005(03)00174-6
Paściak G., Mielcarek W., Prociów K., Warycha J. // Ceram. Int. 2014. V. 40. № 8. P. 12783. https://doi.org/10.1016/j.ceramint.2014.04.132
Meunier M., Izquierdo R., Hasnaoui L. et al. // Appl. Surf. Sci. 1998. V. 127–129. P. 466. https://doi.org/10.1016/S0169-4332(97)00674-0
Tetsuya K., Miyachi Y., Shimanoe K., Yamazoe N. // Sens. Actuators, B. 2001. V. 80. № 1. P. 28. https://doi.org/10.1016/S0925-4005(01)00878-4
Kim H.J., Choi J.W., Kim S.D., Yoo K.S. // Mater. Sci. Forum. 2007. V. 544–545. P. 925. https://doi.org/10.4028/www.scientific.net/MSF.544-545.925
Jalalian-Khakshour A., Phillips Ch., Jackson L. et al. // J. Mater. Sci. 2020. V. 55. P. 2291. https://doi.org/10.1007/s10853-019-04162-8
Naqash S., Sebold D., Tietz F., Guillon O. // J. Am. Ceram. Soc. 2019. V. 102. № 3. P. 1057. https://doi.org/10.1111/jace.15988
Yang G., Zhai Y., Yao J. et al. // Chem. Commun. 2021. V. 57. P. 4023. https://doi.org/10.1039/d0cc07261c
Noguchi Y., Kobayashi E., Plashnitsa L.-S. et al. // Electrochim. Acta. 2013. V.101. P. 59. https://doi.org/10.1016/j.electacta.2012.11.038
Fuentes R.O., Marques F.M.B., Franco J.I. // Bol. Soc. Esp. Ceram. Vidrio. 1999. V. 38. № 6. P. 631.
Fuentes R.O., Figueiredo F., Marques F.-M.B., Franco J.I. // Solid State Ionics. 2001. V. 139. № 3–4. P. 309. https://doi.org/10.1016/S0167-2738(01)00683-X
Fuentes R.O., Figueiredo F.M., Marques F.M.B., Franco J.I. // Solid State Ionics. 2001. V. 140. № 1–2. P. 173. https://doi.org/10.1016/S0167-2738(01)00701-9
Shimizu Y., Azuma Y., Michishita S. // J. Mater. Chem. 1997. V. 7. P. 1487.
Naqash S., Tietz F., Yazhenskikh E. et al. // Solid State Ionics. 2019. V. 336. P. 57. https://doi.org/10.1016/j.ssi.2019.03.017
Грищенко Д.Н., Курявый В.Г., Подгорбунский А.Б., Медков М.А. // Журн. неорган. химии. 2023. № 1. С. 17. https://doi.org/10.31857/S0044457X22601043
Грищенко Д.Н., Дмитриева Е.Э., Медков М.А. // Хим. технология. 2022. Т. 23. № 10. С. 418. https://doi.org/10.31044/1684-5811-2022-23-10-418-423
Narayanan S., Reid S., Butler S., Thangadurai V. // Solid State Ionics. 2019. V. 331. P. 22. https://doi.org/10.1016/j.ssi.2018.12.003
Rao Y.B., Bharathi K.K., Patro L.N. // Solid State Ionics. 2021. V. 366–377. P. 115671. https://doi.org/10.1016/j.ssi.2021.115671
Wang H., Zhao G., Wang S. et al. // Nanoscale. 2022. V. 14. № 3. P. 823. https://doi.org/10.1039/d1nr06959d