Spherical polymer gels containing sulfonate groups: synthesis and adsorption properties

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Abstract

Porous cross-linked polyelectrolyte microspheres with diameter from 1 to 5 μm based on para-styrene sulfonate or copolymer of para-styrene sulfonate with vinyl acetate were synthesized. The content of sulfonate groups in the obtained polyelectrolyte microspheres is more than 2 mmol/g. It was shown that introduction of hydrophobic comonomer significantly increased the degree of swelling of polyelectrolyte microspheres. It was found that the value of adsorption of model compounds (fuchsin, methylene blue) significantly exceed the concentration of sulfonate groups. Morphology, structure of the surface layer of polyelectrolyte matrices were studied by optical and scanning electron microscopy, FTIR spectroscopy, specific surface by the BET method.

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S. G. Laishevkina

Филиал федерального государственного бюджетного учреждения «Петербургский институт ядерной физики им. Б.П. Константинова Национального исследовательского центра «Курчатовский институт»

Email: natali.shevchenko29@gmail.com

Институт высокомолекулярных соединений

Russian Federation, 199004, Санкт-Петербург, Большой пр. В.О., 31

L. M. Druian

Филиал федерального государственного бюджетного учреждения «Петербургский институт ядерной физики им. Б.П. Константинова Национального исследовательского центра «Курчатовский институт»

Email: natali.shevchenko29@gmail.com

Институт высокомолекулярных соединений

Russian Federation, 199004, Санкт-Петербург, Большой пр. В.О., 31

O. D. Iakobson

Филиал федерального государственного бюджетного учреждения «Петербургский институт ядерной физики им. Б.П. Константинова Национального исследовательского центра «Курчатовский институт»

Email: natali.shevchenko29@gmail.com

Институт высокомолекулярных соединений

Russian Federation, 199004, Санкт-Петербург, Большой пр. В.О., 31

Е. М. Ivankova

Филиал федерального государственного бюджетного учреждения «Петербургский институт ядерной физики им. Б.П. Константинова Национального исследовательского центра «Курчатовский институт»

Email: natali.shevchenko29@gmail.com

Институт высокомолекулярных соединений

Russian Federation, 199004, Санкт-Петербург, Большой пр. В.О., 31

B. М. Shabsels

Филиал федерального государственного бюджетного учреждения «Петербургский институт ядерной физики им. Б.П. Константинова Национального исследовательского центра «Курчатовский институт»

Email: natali.shevchenko29@gmail.com

Институт высокомолекулярных соединений

Russian Federation, 199004, Санкт-Петербург, Большой пр. В.О., 31

N. N. Shevchenko

Филиал федерального государственного бюджетного учреждения «Петербургский институт ядерной физики им. Б.П. Константинова Национального исследовательского центра «Курчатовский институт»

Author for correspondence.
Email: natali.shevchenko29@gmail.com

Институт высокомолекулярных соединений

Russian Federation, 199004, Санкт-Петербург, Большой пр. В.О., 31

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Supplementary files

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2. Fig. 1. Schematic arrangement of emulsifiers at the water-cyclohexane interface.

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3. Fig. 2. Particle size distribution for PSSt particles (a) and P(SSt-so-VA) copolymer (b).

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4. Fig. 3. Optical microscopy micrographs of PSSt (a) and P(SSt-so-VA) particles (d); SEM micrographs of PSSt particles (b, c) and P(SSt-so-VA) copolymer particles (e, f).

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5. Fig. 4. IR spectra of CCt-Na (green), IBA (blue) and synthesized PSSt (red) and P(CCt-so-VA) particles (black).

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6. Fig. 5. Content of sulfonate groups in the synthesized particles determined by conductometric titration (orange) and by ion exchange capacity measurement (blue).

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7. Fig. 6. Schematic of the interaction of microspheres with fuchsin (a) and methylene blue (b).

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8. Fig. 7. Adsorption isotherms of fuchsin (a) and methylene blue (b) on the synthesized microspheres.

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9. Fig. 8. Linear correlations of Langmuir isotherms for fuchsin (a) and methylene blue (b); linear correlations of Freundlich isotherms for fuchsin (c) and methylene blue (d).

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