Transformations of Asphaltenes A1 and A2 During Atmospheric Residue Cracking

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In this work, various conditions for cracking the atmospheric residue of the Novokuibyshevsk oil refinery are considered and analyzed. The optimal conditions for cracking the atmospheric residue have been established as a temperature of 450°С and a duration of 30 minutes. These conditions result in an additional 51.8 wt % of light fractions due to the destruction of 31.3 wt % of resin-asphaltene components. The study also examines the compaction products formed during cracking. The study analyzed two fractions of asphaltenes (A1 and A2) isolated from liquid cracking products using the method of structural group analysis. It was found that the duration of atmospheric cracking had an impact on the formation of secondary asphaltenes.

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作者简介

N. Sviridenko

Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: nikita26sviridenko@gmail.com
俄罗斯联邦, Tomsk

N. Sergeyev

Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: nikitaser99@gmail.com
俄罗斯联邦, Tomsk

Kh. Urazov

Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: urazovhh@gmail.com
俄罗斯联邦, Tomsk

参考

  1. Matuszewska A., Owczuk M., Biernat K. // Energies. 2022. V. 15. P. 2719. https://doi.org/10.3390/ en15082719
  2. Sviridenko N.N., Urazov Kh.Kh. // Pet. Sci. Technol. 2023. 41. 20. P. 1918-1933. https://doi.org/10.1080/10916466.2022.2104872
  3. Гончаров А.В., Кривцов Е.Б., Юрлов С.С. // ХТТ. 2022. 2. С. 56. https://doi.org/10.31857/S0023117722020025 [Goncharov, A. V. Krivtsov E. B., Yurlov S. S. // Solid Fuel Chemistry. 2022, vol. 56, no. 2, p. 138–144. https://doi.org/10.3103/S0361521922020021].
  4. Иовик Ю.А., Кривцов Е.Б. // Химия в интересах устойчивого развития. 2020. 4. C. 439. https://doi.org/10.15372/KhUR2020249 [Iovik Y.A., Krivtsov E.B. // Chemistry for Sustainable Development. 2020. 4. p. 425. https://doi.org/10.15372/CSD2020249].
  5. Бояр С.В., Копытов М.А. // ХТТ. 2023. 2 – 3. С. 92. https://doi.org/10.31857/S0023117723020020 [Boyar, S.V., Kopytov, M.A. Solid Fuel Chem. 2023, vol. 57, p. 82. https://doi.org/10.3103/S0361521923020027].
  6. Yakubov M.R., Abilova G.R., Yakubova S.G., Mironov N.A. // Pet. Chem. 2020. V. 60. P. 637. https://doi.org/10.1134/S0965544120060109
  7. Yoshikazu S., Yukichi H., Yoshiaki S., Tugsuu T., Enkhsaruul B. // J. Jpn. Petrol. Inst. 2013. V. 56. 1. P. 44. https://doi.org/10.1627/jpi.56.44
  8. Akimov A.S., Sviridenko N.N. // Pet. Sci. Technol. 2022. V. 40. 8. P. 980. https://doi.org/10.1080/10916466.2021.2008973
  9. Manasrah A.D., Nassar N.N. // Applied Energy. 2020. V. 28. P. 115890. https://doi.org/10.1016/j.apenergy.2020.115890
  10. Oh K.S. // J. Korean Chem. Soc. 2014. 31. P. 151. https://doi.org/10.12925/jkocs.2014.31.1.151
  11. Нальгиева Х.В., Копытов М.А. // ХТТ. 2022. № 2. С. 34. https://doi.org/10.31857/S0023117722020074 [Nal’gieva Kh. V., Kopytov M.A. // Solid Fuel Chemistry, 2022, vol. 56, no. 2, p. 116. https://doi.org/10.3103/S0361521922020070

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2. Fig. 1. Fractional composition of atmospheric residue cracking products

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3. Fig. 2. IR spectra of compaction products after cracking of atmospheric residue at duration: 1 - 30 min; 2 - 60 min

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4. Fig. 3. Averaged molecules of asphaltenes A1 and A2 of initial fuel oil and its cracking products

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