Cross-linking of brominated poly(1-trimethylsilyl-1-propyne) using polyethylenimine as a cross-linking agent

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

In this work cross-linked polymer membranes were obtained by heat treatment of films prepared from a solution containing a mixture of brominated poly(1-trimethylsilyl-1-propyne) [PTMSP] and polyfunctional amine polyethylenimine [PEI] as a cross-linking agent. The cross-linked products were identified on the basis of IR spectra, elemental analysis data, and the stability of the reaction products to the solvent (CCl4) in which the original brominated PTMSP is soluble. According to the IR spectra, the crosslinking reaction occurs via the reactive C-Br bond in bromine-containing PTMSP with the participation of PEI amino groups at temperatures above 90°C. Cross-linking of bromine-containing PTMSP makes it resistant to organic solvents. An increase of PEI-content in the mixture correlates with an increase in the proportion of bromine atoms that have reacted. The cross-linked polymer transport parameters were studied for individual gases and in a methane/n-butane mixture (98.4 mol.% methane and 1.6 mol.% n-butane). In the series PTMSP – brominated PTMSP-Br – PTMSP-Br/PEI (before cross-linking) – PTMSP-Br/PEI (after cross-linking) the permeability to individual gases decreases. Cross-linked PTMSP in a methane/n-butane mixture demonstrates high permeability coefficients of n-butane (P n-C4H10 = 12000 Barrer) and selectivity for the release of n-butane from a mixture with methane (α n-C4H10/CH4 = 13).

作者简介

V. Makrushin

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: matson@ips.ac.ru
俄罗斯联邦, Moscow, 119991

A. Kossov

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
俄罗斯联邦, Moscow, 119991

E. Litvinova

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
俄罗斯联邦, Moscow, 119991

G. Bondarenko

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
俄罗斯联邦, Moscow, 119991

S. Matson

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
俄罗斯联邦, Moscow, 119991

参考

  1. Galizia M., Chi W.S., Smith Z.P., Merkel T.C., Baker R.W., Freeman B.D. // Macromolecules. 2017. V. 50. P. 7809.
  2. Ong Y.K., Shi G.M., Le N.L., Tang Y.P., Zuo J., Nunes S. P., Chung T. S. // Prog. Polym. Sci. 2016. V. 57. P. 1.
  3. Car A., Stropnik C., Yave W., Peinemann K.V. // Adv. Funct. Mater. 2018. V. 18. P. 2815.
  4. Pinnau I., Toy L.G. // J. Membr. Sci. 1996. V. 116. P. 199.
  5. Plate N.A., Bokarev A.K., Kaliuzhnyi N.E., Litvinova E.G., Khotimskii V.S., Volkov V.V., Yampolski Yu.P. // J. Membr. Sci. 1991. V. 60. P. 13.
  6. Yakovlev A.V., Shalygin M.G., Matson S.M., Khotimskiy V.S., Teplyakov V.V. // J. Membr. Sci. 2013. V. 434. P. 99.
  7. Trusov A., Legkov S., van den Broeke L.J.P., Goetheer E., Khotimsky V., Volkov A. // J. Memb. Sci. 2011. V. 383. P. 241.
  8. Consolati G., Genco I., Pegoraro M., Zanderighi L. // J. Polym. Sci. Part B: Polym. Phys. 1996. V. 34. P. 357.
  9. Langsam M., Robeson L. M. // Polym. Eng. Sci. 1989. V. 29. P. 44.
  10. Hachisuka H., Kito H., Tsujita Y., Takizawa A., Kinoshita T. // J. Appl. Polym. Sci. 1988. V. 35, P. 1333.
  11. Tanaka A., Nitta K., Maekawa R., Masuda T., Higashimura T. // Polym. J. 1992. V. 24. P. 1173.
  12. Nagai K., Higuchi A., Nakagawa T. // J. Polym. Sci. B: Polym. Phys. 1995. V. 33. P. 289.
  13. Wind J. D., Staudt-Bickel C., Paul D. R., Koros W. J. // Macromolecules. 2003. V. 36. Р. 1882.
  14. Hillock A. M. W., Koros W. J. // Macromolecules. 2007. V. 40. Р. 583.
  15. Kraftschik B., Koros W. J. // Macromolecules. 2013. V. 46. Р. 6908.
  16. Eguchi H., Kim D. J., Koros W. J. // Polymer. 2015. V. 58. Р. 121.
  17. Masuda T., Isobe E., Higashimura T. // Macromolecules. 1985. V. 18. Р. 841.
  18. Baker R. W. Membrane technology and applications. John Wiley & Sons, 2012.
  19. Kim S., Lee Y.M. // Prog. Polym. Sci. 2015. V. 43. P. 1.
  20. Song Q., Shuai C., Pritchard R.H., Ghalei B., Al-Muhtaseb S.A., Terentjev E.M., Cheetham A.K., Sivaniah E. // Nat. Commun. 2014. V. 5. P. 4813.
  21. Calle M., Jo H.J., Doherty C.M., Hill A.J., Lee Y.M. // Macromolecules.2015. V. 48. P. 2603.
  22. Krol J.J., Boerrigter M., Koops G.H. // J. Membr. Sci. 2001. V. 184. P. 275.
  23. Ismail A.F., Lorna W. // Separ. Purif. Technol. 2002. V. 27. P.173.
  24. Chung T.S., Ren J., Wang R., Li D.F., Liu Y., Pramoda K.P., Cao C., Loh W.W. // J. Membr. Sci. 2003. V 214. P. 5769.
  25. Dudley C.N., Shoeberl B., Sturgill G.K., Beckham H.W., Rezac M.E. // J. Membr. Sci. 2001. V. 191. P. 1.
  26. Khan M.M., Bengston G., Shishatskiy S., Gacal B.N., Rahman Md.M., Neumann S., Filiz V., Abetz V. // Eur. Polym. J. 2013. V. 49. P. 4157.
  27. McCaig M.S., Paul D.R. // Polymer. 1999. V. 40. P. 7209.
  28. Jia J., Baker G.L. // J. Polym. Sci. Part B: Polym. Phys. 1998. V. 36. P. 959.
  29. Kelman S.D., Matteucci S., Bielawski C.W., Freeman B.D. // Polymer. 2007. V. 48. P. 6881.
  30. Nagai K., Masuda T., Nakagawa T., Freeman B.D. // Prog. Polym. Sci. 2001. V. 26. P. 721.
  31. Low B.T., Xiao Y., Chung T.S., Liu Y. // Macromolecules. 2008. V. 41. P. 1297.
  32. Vanherck K., Cano-Odena A., Koeckelberghs G., Dedroog T., Vankelecom I. // J. Membr. Sci. 2010. V. 353. P. 135.
  33. Hillock A.M.W., Koros W.J. // Macromolecules. 2007. V. 40. P. 583.
  34. Wind J.D., Paul D.R., Koros W.J. // J. Membr. Sci. 2004. V. 228. P. 227.
  35. Wind J.D., Staudt-Bickel C., Paul D.R., Koros W.J. // Macromolecules. 2003. V. 36. P. 1882.
  36. Hung W.S., Tsou C.H., De Guzman M., An Q.F., Liu Y.L., Zhang Y.M., Hu C.C., Lee K.R., Lai J.Y. // Chem. Mater. 2014. V. 26. P. 2983.
  37. Jia Z., Wang Y., Shi W., Wang J. // J. Membr. Sci. 2016. V. 520. P. 139.
  38. Aziz F., Ismail A.F. // Sep. Pur. Tech. 2010. V. 73. P. 421.
  39. Tin P.S., Chung T.S., Liu Y., Wang R., Liu S.L., Pramoda K.P. // J. Membr. Sci. 2003. V. 225. P. 77.
  40. Liu Y., Wang R., Chung T.S. // J. Membr. Sci. 2001. V. 189. P. 231.
  41. Zhang S., Li C., Xie X., Zhang F. // Int. J. Hydrog. Ener. 2014. V. 39. P. 13718.
  42. Shao L., Liu L., Cheng S.X., Huang Y.D., Ma J. // J. Membr. Sci. 2008. V. 312. P. 174.
  43. Qiao X.Y., Chung T.S. // AIChE J. 2006. V. 52. P. 3462.
  44. Shao L., Chung T.S., Goh S.H., Pramoda K.P. // J. Membr. Sci. 2005. V. 267. P. 78.
  45. Shao L., Lau C.H., Chung T.S. // Int. J. Hydrog. Energy. 2009. V. 34. P. 8716.
  46. Mangindaan D.W., Shi G.M., Chung T.S. // J. Membr. Sci. 2014. V. 458. P. 76.
  47. Chung T.-S., Shao L., Tin P. S. // Int. J. Hydrog. Ener. 2006. V. 27. P. 998.
  48. Omidvar M., Stafford C. M., Lin H. // J. Membr. Sci. 2019. V. 575. Р. 118.
  49. Abdul Nasir N. A., Ling J. H., Junaidi M. U. M., Hashim N. A., Hizzaddin H. F., Rabuni M. F., Abidin M. I. I. Z., Rohani R. // Asia‐Pac. J. Chem. Eng. 2020. V. 15. P. e2411.
  50. Li H., Yu N., Gellrich F., Reumert A. K., Kraglund M. R., Dong J., Aili D., Yang J. //J. Memb. Sci. 2021. V. 633. P. 119418.
  51. Xu S., Liu L., Wang Y. // Sep. Pur. Tech. 2017. V. 185. P. 215.
  52. Gao J., Sun S.P., Zhu W.P., Chung T.S. // J. Membr. Sci. 2014. V. 452. P. 300.
  53. Shao L., Chung T.S., Goh S.H., Pramoda K.P. // J. Membr. Sci. 2004. V. 238. P. 153.
  54. Xiao Y., Chung T.S., Chung M.L. // Langmuir. 2004. V. 20. P. 8230.
  55. Vanherck K., Vandezande P., Aldea S.O., Vankelecom I.F.J. // J. Membr. Sci. 2008. V. 320. P. 468.
  56. See-Toh Y.H., Silva M., Livingston A. // J. Membr. Sci. 2008. V. 324. P. 220.
  57. Vanherck K., Koeckelberghs G., Vankelecom I.F. // Prog. Polym. Sci. 2013. V. 38. P. 874.
  58. Tashvigh A.A., Luo L., Chung T.S., Weber M., Maletzko C. // J. Membr. Sci. 2018. V. 545. P. 221.
  59. Farahani M.H.D.A., Hua D., Chung T.S. // J. Membr. Sci. 2018. V. 548. P. 319.
  60. Ge Q.,Liang X., Ding L., Hou J., Miao J., Wu B., Yang Z., Xu T. // J. Memb. Sci. 2019. V. 573. P. 595.
  61. Matson S.M., Litvinova E.G., Chernikov V.K., Bondarenko G.N., Khotimskiy V.S. // Polymer. 2021. V. 236. P. 124308.
  62. Ba C., Langer J., Economy J. // J. Membr. Sci. 2009. V. 327. P. 49.
  63. Khotimsky V.S., Tchirkova M.V., Litvinova E.G., Rebrov A.I., Bondarenko G.N. // J. Polym. Sci. A: Polym. Chem. 2003. V. 41. P. 2133.
  64. Полевая В.Г., Бондаренко Г.Н., Шандрюк Г.А., Должикова В.Д., Хотимский В.С // Изв. Ак. Наук. Сер. Хим. 2016. № 4. С. 1067.
  65. Макрушин В.П., Черников В.К., Левин И.С., Коссов А.А., Матсон С.М. // Мембраны и мембранные технологии. 2023. Т. 13. С. 172.
  66. Yave W., Peinemann K. V., Shishatskiy S., Khotimskiy V., Chirkova M., Matson S., Litvinova E., Lecerf, N. // Macromolecules.2007. V. 40. P. 8991.

补充文件

附件文件
动作
1. JATS XML
下载

版权所有 © Russian Academy of Sciences, 2024