Himičeskaâ fizikaHimičeskaâ fizikaХимическая физика0207-401XThe Russian Academy of Sciences68649710.31857/S0207401X25060018СТРОЕНИЕ ХИМИЧЕСКИХ СОЕДИНЕНИЙ, КВАНТОВАЯ ХИМИЯ, СПЕКТРОСКОПИЯСтроение химических соединений, квантовая химия, спектроскопияResearch ArticleFluorescent Photoswitchable SystemsФлуоресцентные фотопереключаемые системыBudykaМ. F.БудыкаМ. Ф.
Russian Federation
budyka@icp.ac.ruFederal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of SciencesФедеральный исследовательский центр проблем химической физики и медицинской химии Российской академии наук040620254463290107202501072025Copyright ©; 2025, Russian Academy of SciencesCopyright ©; 2025, Российская академия наук2025Russian Academy of SciencesРоссийская академия наукhttps://transsyst.ru/0207-401X/article/view/686497

Fluorescent photoswitchable systems (FPSS) are organic molecular and organic-inorganic hybrid nanoscale systems that combine the properties of photochromes and fluorophores, i.e. the ability to change their fluorescent properties, intensity and/or emission spectrum under the action of light. The structure and mechanisms of action of FPSS of different types are considered, examples of application of FPSS in super-resolution microscopy, for visualisation of biological and inorganic nano-objects, recording of optical information, for anti-counterfeiting, as photonic molecular logic gates are given.

Флуоресцентные фотопереключаемые системы (ФФПС) – это органические молекулярные и органо-неорганические гибридные наноразмерные системы, объединяющие в себе свойства фотохромов и флуорофоров, т.е. способность под действием света изменять свои флуоресцентные свойства, интенсивность и/или спектр излучения. Рассмотрено строение и механизмы действия ФФПС разного типа, даны примеры применения ФФПС в микроскопии сверхвысокого разрешения, для визуализации биологических и неорганических нанообъектов, записи оптической информации, для борьбы с контрафактом, в качестве фотонных молекулярных логических вентилей.

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