Crystal and Molecular Structure of Binuclear Technetium Carbonyl Chloride Complexes: [99TcCl(CO)3(C5H8O2)]2 (C5H8O2 = Acetylacetone) and [99TcCl(CO)4]2

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Abstract

The crystal and molecular structures of the complex [99TcCl(CO)3(C5H8O2)]2 (C5H8O2 = Hacac = acetylacetone) formed in the course of prolonged standing of a [99Tc(acac)(CO)4] solution in ССl4/CDCl3 and of its analog containing no organic ligand, [99TcCl(CO)4]2, were determined. Both complexes contain a [Tc2(μ-Cl)2] four-membered ring. The remaining sites in the coordination sphere of the Tc atom are occupied by carbonyl ligands, and in the case of [99TcCl(CO)3(Hacac)]2, also by the neutral acetylacetone molecule. The Hacac molecules in the binuclear complex are in the cis position to the Cl atoms in the octahedral surrounding of the Тс atoms and in the trans position to each other relative to the [Tc2(μ-Cl)2] ring. A comparative analysis of the geometries of the complexes and their known analogs was performed.

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About the authors

G. V. Sidorenko

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

Author for correspondence.
Email: gevasid@mail.ru
Russian Federation, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783

A. E. Miroslavov

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI; St. Petersburg State University

Email: gevasid@mail.ru
Russian Federation, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783; Universitetskaya nab. 7/9, St. Petersburg, 199034

V. V. Gurzhiy

St. Petersburg State University

Email: gevasid@mail.ru
Russian Federation, Universitetskaya nab. 7/9, St. Petersburg, 199034

A. R. Kochergina

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI; St. Petersburg State University

Email: gevasid@mail.ru
Russian Federation, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783; Universitetskaya nab. 7/9, St. Petersburg, 199034

A. P. Sakhonenkova

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

Email: gevasid@mail.ru
Russian Federation, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783

M. Yu. Tyupina

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

Email: gevasid@mail.ru
Russian Federation, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783

L. S. Chistyi

Research Institute of Hygiene, Professional Pathology, and Human Ecology, Federal Medical-Biological Agency

Email: gevasid@mail.ru
Russian Federation, Zavodskaya ul. 6/2, korp. 93, Kuzmolovskii, Vsevolozhsk raion, Leningrad oblast, 188663

E. A. Pechertseva

Khlopin Radium Institute

Email: gevasid@mail.ru
Russian Federation, 2-i Murinskii pr. 28, St. Petersburg, 194021

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2. Fig. 1. Molecular structure of the complex [99TcCl(CO)4]2.

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3. Fig. 2. Packing of [TcCl(CO)4]2 molecules in the crystal lattice, projection on the ab (a) and as (b) planes. The contours of the unit cell are shown.

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4. Fig. 3. Molecular structure of the complex [99TcCl(CO)3(Hacac)]2.

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5. Fig. 4. Packing of [TcCl(CO)3(Hacac)]2 molecules in the crystal lattice, projection on the bc (a) and ab (b) plane. The contours of the unit cell are shown.

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